S31200 is a nitrogen-bearing ferritic-austenitic (duplex) stainless steel with a microstructure of roughly equal ferrite and austenite. This datasheet presents the material within the American standard system.
With about 25% chromium, 6% nickel, 1.7% molybdenum and a deliberate nitrogen addition (0.14-0.20%), S31200 provides roughly twice the yield strength of standard austenitic grades, with good resistance to chloride pitting, crevice corrosion and especially chloride stress-corrosion cracking. The nitrogen addition stabilises austenite, raises strength and improves pitting resistance, giving a PREN around 33.
Typical applications include heat exchangers, condensers and process equipment in chloride-bearing waters, and components for the chemical, marine and oil-and-gas industries requiring high strength with chloride-SCC resistance.
Values for the solution-annealed condition.
| Property | Value | Unit |
|---|---|---|
| Density | 7.7 | g/cm³ |
| Melting range | 1390-1430 | °C |
| Young's modulus (20 °C) | 200 | GPa |
| Thermal conductivity (20 °C) | 16 | W/m·K |
| Coefficient of thermal expansion (20-100 °C) | 13 | µm/m·°C |
| Specific heat (20 °C) | 480 | J/kg·K |
| Magnetic response | Ferromagnetic (duplex) | — |
Composition per ASTM A240.
| Element | Symbol | Min % | Max % | Role in Alloy |
|---|---|---|---|---|
| Iron | Fe | Balance | — | Base element |
| Chromium | Cr | 24.0 | 26.0 | Ferrite former; corrosion resistance |
| Nickel | Ni | 5.5 | 6.5 | Austenite former; phase balance |
| Molybdenum | Mo | 1.2 | 2.0 | Pitting + crevice resistance |
| Nitrogen | N | 0.14 | 0.20 | Austenite former; strength; pitting |
| Manganese | Mn | — | 2.0 | Deoxidiser |
| Silicon | Si | — | 1.0 | Deoxidiser |
| Carbon | C | — | 0.030 | Low (intergranular resistance) |
| Phosphorus | P | — | 0.045 | Residual impurity |
| Sulphur | S | — | 0.030 | Residual impurity |
Nominal: 25Cr-6Ni-1.7Mo-N duplex. PREN ~33.
Solution-annealed condition, per ASTM A240 for UNS S31200.
| Property | Value | Unit |
|---|---|---|
| Tensile strength | >=690 | MPa |
| 0.2% yield strength | >=450 | MPa |
| Elongation at break | >=25 | % |
| Brinell hardness | <=280 | HB |
| Rockwell hardness | <=31 | HRC |
Typical solution-annealed values are higher (UTS ~780 MPa, yield ~510 MPa). Confirm against the mill test report.
| Environment | Performance | Notes |
|---|---|---|
| Chloride SCC | Excellent | Key duplex advantage over austenitics |
| Chloride pitting | Good | Cr + Mo + N (PREN ~33) |
| Crevice corrosion | Good | Better than 316L |
| General (oxidizing) | Very good | High chromium |
| Sulphide / sour | Good | Listed in NACE MR0175 |
The duplex structure gives far better chloride-SCC resistance than austenitic 304/316.
Not hardenable by heat treatment; properties are set by solution annealing and phase balance.
Solution Anneal approximately 1040-1100 °C, followed by rapid water quench to retain the balanced ferrite-austenite structure and avoid embrittling intermetallic phases. Avoid prolonged exposure in the 300-900 °C range (sigma-phase / 475 °C embrittlement).
Weldable by common fusion and resistance methods; should not be joined by oxyacetylene welding. Use a matching or over-alloyed duplex/Ni-base filler and control heat input to maintain phase balance.
| Process | Applicability | Filler / Consumable |
|---|---|---|
| GTAW / TIG | Good | Duplex (e.g. ER2209) or Ni-base |
| GMAW / MIG | Good | Duplex (e.g. ER2209) |
| SMAW / stick | Good | Matching duplex electrode |
No preheat; control interpass temperature; a post-weld solution anneal + quench restores optimum phase balance on heavy sections.
Machining Guidelines
| Parameter | Recommendation |
|---|---|
| Machinability | Duplex; rigid setup, sharp tooling, moderate speeds |
| Work hardening | Significant; positive feeds, avoid dwelling |
| Coolant | Ample flood coolant |
Forming Processes
| Process | Notes |
|---|---|
| Hot forming | ~1200-950 °C; solution anneal + quench afterward |
| Cold forming | Higher forces than austenitics; lower ductility |
| Industry | Typical Components | Key Requirements |
|---|---|---|
| Chemical processing | Heat exchangers, condensers | Chloride SCC + pitting resistance |
| Oil & gas | Tubing, process components | Sour-service resistance |
| Marine | Seawater heat exchangers | Chloride SCC resistance |
| Pulp & paper | Process equipment | Chloride + caustic resistance |
| Product Form | Standard | Notes |
|---|---|---|
| Plate, sheet and strip | ASTM A240 / ASME SA-240 · UNS S31200 | — |
| Bar and shapes | ASTM A276 / A479 · UNS S31200 | — |
| Seamless / welded tube | ASTM A789 · UNS S31200 | — |
| Seamless / welded pipe | ASTM A790 · UNS S31200 | — |
| Forgings / fittings | ASTM A182 · UNS S31200 | — |
| Sour service | NACE MR0175 / ISO 15156 | Acid-gas applications |
Nitrogen-bearing ferritic-austenitic (duplex) stainless steel. UNS S31200.
| UNS | Cr % | Ni % | Mo % | N % | Best Used For |
|---|---|---|---|---|---|
| S31200 | 24-26 | 5.5-6.5 | 1.2-2.0 | 0.14-0.20 | N-bearing duplex; chloride-SCC service |
| S32900 | 23-28 | 2.5-5.0 | 1.0-2.0 | — | Early duplex (no N spec) |
| S31803 | 22-23 | 4.5-6.5 | 3.0-3.5 | 0.14-0.20 | Standard duplex (higher PREN) |
| S32750 | 24-26 | 6.0-8.0 | 3.0-5.0 | 0.24-0.32 | Super duplex |
| S31603 | 16-18 | 10-14 | 2.0-3.0 | — | Austenitic general service |




