Austenitic

Austenitic

S21800

Overview

S21800 is a nitrogen-strengthened, high-silicon, high-manganese austenitic chromium-nickel stainless steel (nominally 17% chromium, 8.5% nickel, 8% manganese, 4% silicon — the "17-8-8" type) developed primarily as a wear- and galling-resistant alloy. This datasheet presents the material within the American standard system.

It is fully austenitic, and the deliberate additions of silicon and manganese create a matrix that inhibits wear, galling and fretting even in the annealed condition — giving wear and galling resistance comparable to cobalt-based (Stellite-type) alloys but without the cost or machining difficulty of a cobalt alloy. Its room-temperature yield strength is approximately twice that of Types 304 and 316. The general corrosion resistance falls between Types 304 and 316, but it offers superior chloride-pitting, stress-corrosion-cracking and crevice-corrosion resistance to Type 316, and its high-temperature oxidation resistance is similar to Type 309, with useful properties to about 982 °C (1800 °F). It also retains good impact toughness at low temperature and is essentially non-magnetic. Cold work raises strength and hardness but does not further enhance the anti-galling behaviour, which is inherent in the annealed matrix.

Typical applications include valve stems, seats and trim, fastening systems, pins, bushings and roller bearings, pump shafts and rings, wear rails and screening — particularly where galling or seizure must be avoided without resorting to cobalt- or high-nickel-based hardfacing.

1. Physical Properties

Values per manufacturer / reference data, annealed condition.

Property Value Unit
Density 7.62 g/cm³
Melting range 1372–1414 °C
Maximum service temperature (oxidizing) ~982 (1800 °F) °C
Young's modulus (20 °C) 193 GPa
Thermal conductivity (20 °C) ~14.6 W/m·K
Coefficient of thermal expansion (20–100 °C) ~16.7 µm/m·°C
Electrical resistivity (20 °C) ~0.91 µΩ·m
Magnetic response Non-magnetic (austenitic)

2. Chemical Composition (wt %)

Limiting composition per ASTM A276 / AMS 5848.

Element Symbol Min % Max % Role in Alloy
Iron Fe Balance Base element
Chromium Cr 16.0 18.0 Passivity; corrosion + oxidation resistance
Manganese Mn 7.0 9.0 Austenite stabiliser; anti-galling matrix
Nickel Ni 8.0 9.0 Austenite stability
Silicon Si 3.5 4.5 Key: anti-galling / anti-wear; oxidation
Nitrogen N 0.08 0.18 Solid-solution strengthening; austenite stability
Molybdenum Mo 0.75 Residual
Copper Cu 0.75 Residual
Carbon C 0.10 Controlled
Phosphorus P 0.040 Residual impurity
Sulphur S 0.030 Residual impurity

Nominal: 17Cr-8.5Ni-8Mn-4Si with nitrogen. The combination of high silicon and manganese is the defining feature — it creates a matrix that resists galling, wear and fretting in the annealed condition, while nitrogen and manganese provide the high strength.

3. Mechanical Properties

Typical room-temperature properties, annealed condition.

Property Value Source
Ultimate tensile strength ~690–760 MPa Annealed
0.2% proof strength (yield) ~415 MPa Annealed
Elongation at break ~35–50 % Annealed
Hardness ~95 HRB Annealed
Low-temperature toughness Good Retained at sub-zero

Room-temperature yield strength is about twice that of Types 304 and 316. Cold work raises strength and hardness (the alloy stays fully austenitic after severe cold work) but does not further improve the anti-galling behaviour. Values are typical; confirm against the mill test certificate.

4. Corrosion, Wear and High-Temperature Resistance

Property / Environment Performance Notes
Galling / wear / fretting Outstanding Inherent in annealed matrix (Si + Mn)
General corrosion Between 304 and 316
Chloride pitting Superior to 316
Stress-corrosion cracking Superior to 316
Crevice corrosion Superior to 316
High-temperature oxidation Similar to 309 To ~982 °C (1800 °F)
Low-temperature toughness Good Sub-zero impact resistance

In a wear system, galling/seizure typically fails first, then wear, then corrosion — so galling and wear resistance are the primary design drivers for this alloy.

5. Heat Treatment

An austenitic stainless steel; it cannot be hardened by heat treatment. High strength comes from nitrogen, manganese and silicon; strength and hardness can be raised by cold work (without improving the inherent anti-galling behaviour).

Solution Anneal approximately 1040–1120 °C, followed by rapid cooling (water quench), to dissolve carbides and produce a uniform austenitic structure; the anti-galling matrix is fully developed in this annealed condition.

The alloy remains fully austenitic and essentially non-magnetic even after severe cold work. Hot working is done in the range ~1095–1175 °C (2000–2150 °F).

6. Weldability and Joining

Can be handled in the weld shop like Types 304 and 316, using a matching Nitronic 60W bare wire — included in AWS A5.9 as ER218. No preheat or post-weld heat treatment is normally required other than normal stress relief in heavy fabrication. Most applications are used in the as-welded condition (except where corrosion resistance governs). Autogenous (fillerless) gas-tungsten-arc fusion welds can be made; such welds are free from cracking and retain galling and cavitation resistance similar to the base metal.

Process Applicability Filler / Consumable
GTAW / TIG · GMAW / MIG Good Nitronic 60W (AWS A5.9 ER218)
SMAW Good Matching ER218-type electrodes
Autogenous GTAW Good None (retains anti-galling)

No preheat or post-weld heat treatment normally required.

7. Machinability and Fabrication

Machining Guidelines

Parameter Recommendation
Machinability As for austenitic stainless but strong/work-hardening; rigid tooling, slower speeds, heavy feeds
Tooling Coated carbide tooling recommended
Work hardening High; positive feeds, avoid dwelling
Coolant Ample flood coolant

Forming Processes

Process Notes
Hot working ~1095–1175 °C (2000–2150 °F)
Cold forming Work-hardens; stays austenitic; more power than 304
Solution anneal ~1040–1120 °C, water quench

8. Applications

Industry Typical Components Key Requirements
Valves Valve stems, seats and trim Anti-galling + corrosion resistance
Fasteners Fastening systems, bolts, nuts (anti-seize) Anti-galling; high strength
Bearings / bushings Pins, bushings, roller bearings, wear rails Wear + galling resistance
Pumps Pump shafts, rings, wear components Wear + corrosion resistance
Process equipment Screening, high-temperature parts Oxidation + wear resistance
General Anti-galling replacement for cobalt hardfacing Cost-effective wear resistance

9. Available Product Forms and Standards

Product Form Standard Notes
Bar, wire, forgings, extrusions, rings, tubing AMS 5848 S21800
Bar and shapes ASTM A276 / A479
Bolting / fasteners ASTM A193 / A194
Plate, sheet and strip ASTM A240 (where listed)
Welding wire AWS A5.9 Nitronic 60W

Nitrogen-strengthened high-silicon high-manganese 17-8-8 wear- and galling-resistant austenitic stainless steel. UNS S21800; AMS 5848; ASTM A276 / A193; AWS A5.9. Tradenames: Nitronic 60, Alloy 218, Gall-Tough Plus.

10. Comparison with Related Alloys (UNS System)

UNS Nominal Strength Best Used For
S21800 17Cr-8.5Ni-8Mn-4Si-N Galling/wear Anti-galling + wear (Si/Mn matrix)
S20910 22Cr-13Ni-5Mn-Mo-Nb-V-N Corrosion + strength Higher corrosion + strength (with Mo)
S21900 21Cr-6Ni-9Mn-N High strength Non-magnetic high strength (no Mo)
S30400 18Cr-8Ni General General stainless (reference)
S31600 17Cr-12Ni-2Mo General + Mo General Mo stainless (reference)


Next:Alloy 218

Click to add WeChat