Austenitic

Austenitic

X2CrNiMnMoNNb21-16-5-3

Overview

X2CrNiMnMoNNb21-16-5-3 is a nitrogen-strengthened, niobium-stabilised, non-magnetic austenitic chromium-nickel-manganese-molybdenum stainless steel (nominally 21% chromium, 16% nickel, 5% manganese, 3% molybdenum — reflected in the EN designation). This datasheet presents the material within the European standard system.

Its high alloy content gives non-magnetic behaviour (relative permeability about 1.04), high tensile and yield strength, and very good corrosion resistance — particularly in seawater and coastal environments. The low carbon content means that welding does not cause chromium-carbide precipitation, so the steel resists intergranular corrosion even in the as-welded (sensitised) condition. The high manganese and nitrogen stabilise the austenite and provide strength, while molybdenum contributes to pitting and crevice resistance. Note that the high manganese content can reduce pitting resistance somewhat relative to an equivalently-alloyed low-manganese steel.

Typical applications include non-magnetic structural components, shipbuilding and marine hardware, high-strength fasteners and shafting, and equipment for the food-and-beverage and chemical industries (cold nitric and organic acids, chloride-bearing media at moderate concentration).

1. Physical Properties

Values per manufacturer data, solution-annealed condition.

Property Value Unit
Density 7.90 g/cm³
Young's modulus (20 °C) ~200 GPa
Thermal conductivity (20 °C) 14 W/m·K
Specific heat capacity (20 °C) 460 J/kg·K
Coefficient of thermal expansion (20–100 °C) 15.7 µm/m·°C
Electrical resistivity (20 °C) 0.70 µΩ·m
Relative magnetic permeability (µr) 1.04 (non-magnetic)
PREN 33.1–38.6

2. Chemical Composition (wt %)

Composition per VdTÜV-Wbl 493 / SEW 390 (W.Nr. 1.3964, X2CrNiMoNNb21-16-5-3).

Element Symbol Min % Max % Role in Alloy
Iron Fe Balance Base element
Chromium Cr 20.0 22.0 Passivity; pitting resistance
Nickel Ni 15.0 17.0 Austenite stability
Manganese Mn 4.0 6.0 Austenite stability; N solubility
Molybdenum Mo 3.0 3.5 Pitting / crevice resistance
Niobium Nb 0.10 0.30 Stabiliser; strengthening
Nitrogen N 0.20 0.40 High strength; pitting resistance
Vanadium V 0.10 0.30 Strengthening
Carbon C 0.030 Very low (intergranular resistance)
Silicon Si 1.0 Deoxidiser
Phosphorus P 0.025 Residual impurity
Sulphur S 0.010 Residual impurity

Nominal: 21Cr-16Ni-5Mn-3Mo-N high-nitrogen austenitic stainless steel. The high nitrogen with manganese gives roughly double the yield strength of standard austenitics while retaining excellent corrosion resistance. The EN composition (Ni 15-17, Mo 3.0-3.5) differs from the US grade.

3. Mechanical Properties

Solution-annealed condition (1020-1050 °C), per VdTÜV-Wbl 493 for W.Nr. 1.3964.

Property Value Unit
Tensile strength (Rm) 700–950 MPa
0.2% proof strength (Rp0.2) ≥365 MPa
Elongation at fracture (A) ≥35 %
Brinell hardness ≤250 HB

Values per EN/DIN; confirm against the inspection certificate (EN 10204).

4. Corrosion Resistance

Environment Performance Notes
Rural / industrial / coastal Excellent
Seawater / chloride-bearing Very good High alloy content
Pitting (chlorides) Good PREN 33.1–38.6 (see note)
Intergranular (as-welded / sensitised) Resistant Low carbon; Nb-stabilised
Cold nitric / organic acids Good Food & beverage (moderate concentration)
Crevice corrosion Good High Mo
Magnetic stability Excellent µr 1.04; stable after cold work

Note: the relatively high manganese content can reduce pitting-corrosion resistance compared with an equivalently-alloyed low-manganese steel. Intergranular-corrosion testing per AFNOR NF A05-159 / ISO 3651 / DIN 50914 confirms resistance after welding.

5. Heat Treatment

An austenitic stainless steel; it cannot be hardened by heat treatment. High strength comes from nitrogen and manganese; strength can be raised further by cold work.

Solution Anneal 1020–1050 °C, followed by rapid cooling in air or water, to dissolve secondary phases and give optimum corrosion resistance and the low magnetic permeability.

Because of the low carbon content, welding does not lead to chromium-carbide formation; the alloy resists intergranular corrosion in the as-welded (sensitised) condition. After forging, rapid cooling in air or water is required to avoid undesirable phases.

6. Weldability and Joining

Has good weldability. Owing to the low carbon content, welding does not result in chromium-carbide formation, and the alloy resists intergranular corrosion in the as-welded condition. Where a filler is required, the matching grades W.Nr. 1.3954 or 1.3984 are used. Post-weld heat treatment is normally unnecessary; if required (extensive cold deformation or heavy wall thickness), the solution anneal is applied.

Process Applicability Filler / Consumable
GTAW / TIG · GMAW / MIG Good Matching W.Nr. 1.3954 / 1.3984
SMAW · SAW Good Matching consumable

No preheat required. Low carbon content resists weld-zone sensitization; post-weld heat treatment normally unnecessary.

7. Machinability and Fabrication

Owing to its high alloy content, 1.3964 is difficult to machine; coated hard-metal (carbide) tooling is recommended.

Machining Guidelines (solution-annealed, Rm 560–640 N/mm²; coated carbide)

Depth of cut (mm) Feed Cutting speed (m/min)
6 0.5 110
3 0.4 125
1 0.2 150

Forming / Forging

Process Notes
Forging Pre-heat 950–1150 °C; forge 900–1100 °C; rapid air/water cool after
Cold forming / cold heading In some instances; work-hardens
Solution anneal 1020–1050 °C, rapid cool

8. Applications

Industry Typical Components Key Requirements
Non-magnetic equipment Non-magnetic structural components Low magnetic permeability (µr 1.04)
Shipbuilding / marine Marine hardware, fittings Seawater + chloride resistance
Fasteners / fittings Bolting, shafting, high-strength parts High strength + corrosion resistance
Food & beverage Process equipment (moderate acid) Corrosion + hygiene
Chemical process Cold nitric / organic-acid service Acid + intergranular resistance
Oil & gas Sour-service components Corrosion + strength

9. Available Product Forms and Standards

Product Form Standard Notes
Bar, rod and semi-finished W.Nr. 1.3964 · EN 10088-3 X2CrNiMnMoNNb21-16-5-3
Plate, sheet and strip W.Nr. 1.3964 · EN 10088-2
Forgings W.Nr. 1.3964
Approvals VdTÜV-Wb 493 · SEW 390 non-magnetic steel
Sour service ISO 15156-3 Acid-gas applications

Nitrogen-strengthened, niobium-stabilised non-magnetic austenitic stainless steel (21Cr-16Ni-5Mn-3Mo). W.Nr. 1.3964 (X2CrNiMnMoNNb21-16-5-3); VdTÜV-Wb 493; SEW 390.

10. Comparison with Related Alloys (EN Symbol System)

EN Symbol Nominal PREN Best Used For
X2CrNiMnMoNNb21-16-5-3 21Cr-16Ni-5Mn-3Mo-Nb-N 33–39 Non-magnetic high-strength + corrosion
X8CrMnMoN18-18 18Cr-18Mn-Mo-N ~30 Non-magnetic (lower cost)
X2CrNiMo17-12-2 17Cr-12Ni-2Mo ~24 General Mo stainless (reference)
X2CrNiMo18-15-4 18Cr-13Ni-3Mo ~30 Higher-Mo stainless (reference)
X2CrNiMoN22-5-3 22Cr-5Ni-3Mo-N ~35 Duplex (similar PREN, higher strength)


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