Austenitic

Austenitic

253 MA

Overview

253 MA is a heat-resistant austenitic chromium-nickel stainless steel with high silicon and nitrogen contents and a rare-earth (cerium) micro-addition, developed for high-temperature service where oxidation resistance, creep strength and long-term structural stability are essential. This datasheet presents the material within the American standard system.

It resists oxidation in air up to about 1150 °C (2100 °F) and provides superior service to the 25Cr-20Ni (310-type) grade in carbon-, nitrogen- and sulphur-bearing atmospheres. Its comparatively low nickel content gives an advantage in reducing sulphidising atmospheres relative to high-nickel alloys. The high chromium and silicon, together with the nitrogen and cerium, give good oxide-scale stability and adherence, high elevated-temperature (creep) strength and excellent resistance to sigma-phase precipitation: cerium suppresses oxide-scale spallation during thermal cycling, silicon forms a protective sub-scale that slows oxygen diffusion, and nitrogen provides solid-solution strengthening. The fully austenitic structure gives excellent toughness, even down to cryogenic temperatures. The most suitable temperature range is about 850–1100 °C; prolonged use in the 600–850 °C range can lead to structural changes (embrittlement).

Typical applications include industrial-furnace components and linings, radiant tubes, muffles and retorts, annealing baskets and heat-treatment fixtures, heat exchangers and recuperators, burner components, and other equipment for high-temperature oxidizing or thermally-cycled service. Resistance to oxidizing/reducing sulphur-bearing gases and to aqueous corrosion is limited.

1. Physical Properties

Values per manufacturer (Outokumpu) / reference data, solution-annealed condition.

Property Value Unit
Density 7.8 g/cm³
Melting range 1380–1430 °C
Maximum service temperature (oxidizing, air) ~1150 °C
Young's modulus (20 °C) 200 GPa
Thermal conductivity (20 °C) ~15 W/m·K
Coefficient of thermal expansion (20–100 °C) ~17 µm/m·°C
Electrical resistivity (20 °C) ~0.85 µΩ·m
Magnetic response Non-magnetic (austenitic)

2. Chemical Composition (wt %)

Composition per ASTM A240.

Element Symbol Value Role in Alloy
Iron Fe Balance Base element
Chromium Cr 20.0–22.0 Oxidation resistance
Nickel Ni 10.0–12.0 Austenite stability
Silicon Si 1.4–2.0 Protective SiO₂ sub-scale; oxidation resistance
Nitrogen N 0.14–0.20 Solid-solution strengthening; creep; austenite stability
Carbon C 0.05–0.10 Creep strength
Cerium Ce ~0.03–0.08 Suppresses oxide-scale spallation (rare earth)
Manganese Mn ≤0.80 Austenite stabiliser
Phosphorus P ≤0.040 Residual impurity
Sulphur S ≤0.015 Residual impurity

Nominal: 21Cr-11Ni with ~1.6% Si, ~0.17% N and a rare-earth (cerium) microaddition. Cr + Si + N + Ce together give oxide-scale stability, creep strength and sigma-phase resistance — a service limit of ~1150 °C, higher than the 153 MA / 304-type grades.

3. Mechanical Properties

Typical room-temperature properties, solution-annealed condition.

Property Value Source
Ultimate tensile strength ~600–800 MPa Annealed
0.2% proof strength (yield) ~310 MPa min Annealed
Elongation at break ≥40 % Annealed
Hardness ~≤200 HB Annealed

The nitrogen addition gives high elevated-temperature (creep) strength, while the fully austenitic structure provides excellent toughness from cryogenic to elevated temperatures. Optimum service is ~850–1100 °C. Values are typical or specified minima; confirm against the mill test certificate.

4. Oxidation and High-Temperature Resistance

Environment Performance Notes
Oxidation / scaling (air) Excellent To ~1150 °C
Thermal cycling Excellent Cerium suppresses scale spallation
Carbon / nitrogen / sulphur atmospheres Good Superior to 310-type
Reducing sulphidising atmospheres Advantageous Low nickel content helps
High-temperature creep strength Excellent Nitrogen-strengthened
Sigma-phase resistance Excellent Cerium / nitrogen
Cryogenic toughness Excellent Fully austenitic
Embrittlement (600–850 °C, prolonged) Caution Structural changes possible

5. Heat Treatment

An austenitic stainless steel; it cannot be hardened by heat treatment. Strength is increased only by cold work.

Solution Anneal approximately 1020–1120 °C (commonly ~1080 °C), followed by rapid cooling in water or air, to dissolve carbides and secondary phases and produce a uniform austenitic structure with optimum oxidation and creep behaviour.

Prolonged exposure in the ~600–850 °C range can cause structural changes (embrittlement); ductility can be restored by re-solution-annealing followed by rapid cooling. The cerium and nitrogen additions help resist sigma-phase precipitation.

6. Weldability and Joining

Has good weldability and can be joined by submerged-arc, plasma-arc, flux-cored-arc, shielded-metal-arc, gas-tungsten-arc and gas-metal-arc processes. A matching or over-alloyed heat-resistant filler (matching 253-type composition) is used; preheating is not required.

Process Applicability Filler / Consumable
GTAW / TIG · GMAW / MAG Good Matching/over-alloyed heat-resistant filler
SAW · PAW · FCAW · SMAW Good Heat-resistant consumable

No preheat required. Keep heat input controlled; solution anneal after welding where maximum high-temperature performance is required.

7. Machinability and Fabrication

Machining Guidelines

Parameter Recommendation
Machinability As for austenitic stainless; sharp tools, slow speeds, heavy feeds
Work hardening High; rigid setup, positive feeds
Coolant Ample flood coolant

Forming Processes

Process Notes
Hot working ~1150–900 °C; solution anneal after
Cold forming Good ductility; cold-roll/draw/bend/deep-draw; work-hardens
Solution anneal ~1020–1120 °C, rapid cool

8. Applications

Industry Typical Components Key Requirements
Heat treating / furnaces Furnace components/linings, radiant tubes, muffles, retorts Oxidation resistance to ~1150 °C
Heat treatment Annealing baskets, fixtures, conveyor parts Creep + thermal-cycling resistance
Power / process Heat exchangers, recuperators High-temperature strength + creep
Combustion Burner components, thermal shields Oxidation + sulphur-gas resistance
Petrochemical High-temperature process equipment Oxidation + creep resistance
Cement / mineral Kiln and high-temperature parts Oxidation + thermal cycling

9. Available Product Forms and Standards

Product Form Standard Notes
Plate, sheet and strip ASTM A240 S30815
Bar and shapes ASTM A276 / A479
Seamless / welded pipe and tube ASTM A312 / A213 / A249 ASME SA213
Forgings / fittings ASTM A182 / A403
Wire ASTM A580

Heat-resistant Si-N-Ce austenitic stainless steel (21Cr-11Ni). UNS S30815; ASTM A240 / A213 / A312; ASME SA213. Tradename / type: 253 MA.

10. Comparison with Related Alloys (Trade-Name System)

Grade Nominal Max °C Best Used For
253 MA 21Cr-11Ni-Si-N-Ce ~1150 High-temp Si-N-Ce; furnace + thermal cycling
153 MA 19Cr-10Ni-Si-N-Ce ~1000 Lower-temp Si-N-Ce (304 upgrade)
304H 18Cr-9Ni ~800 Standard heat-resistant austenitic
310S 25Cr-20Ni ~1050–1100 High-Cr/Ni heat-resistant
353 MA 25Cr-35Ni-Si-N-Ce ~1175 Highest-temp Si-N-Ce (high Ni)


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