Austenitic

Austenitic

1.4818

Overview

1.4818 is a heat-resistant austenitic chromium-nickel stainless steel based on the 18Cr-9Ni (1.4301-type) composition but with increased silicon and nitrogen contents and microalloyed with rare-earth metals (cerium), which together raise its maximum service temperature in dry air to about 1000 °C. This datasheet presents the material within the European standard system.

It is positioned between the standard 1.4301 grade (max ~800 °C) and the more highly-alloyed 1.4835 grade (max ~1150 °C), offering substantially better high-temperature performance than 1.4301 at a lower alloy content and cost than the higher grades. The cerium and silicon improve the stability and adherence of the protective oxide scale, while the nitrogen provides solid-solution strengthening and stabilises the austenite; together they give good oxide stability, resistance to sigma-phase precipitation and good strength at high temperature. The fully austenitic structure also provides excellent toughness down to cryogenic temperatures. Optimum performance is obtained in the range about 600–950 °C, where creep strength is usually the dimensioning factor.

Typical applications include industrial-furnace components, radiant tubes and muffles, heat-treatment fixtures and conveyor parts, automotive exhaust and emission-control components, heat exchangers and recuperators, and other equipment operating at elevated temperature. As with other austenitic grades, resistance is best in oxidizing atmospheres; resistance to oxidizing sulphur-bearing gases is limited.

1. Physical Properties

Property Value Unit
Density 7.8 g/cm³
Melting range 1400–1450 °C
Maximum service temperature (oxidizing, dry air) ~1000 °C
Young's modulus (20 °C) 200 GPa
Thermal conductivity (20 °C) ~15 W/m·K
Coefficient of thermal expansion (20–100 °C) ~17 µm/m·°C
Electrical resistivity (20 °C) ~0.78 µΩ·m
Magnetic response Non-magnetic (austenitic)

2. Chemical Composition (wt %)

Composition per EN 10088-2 / EN 10095 (W.Nr. 1.4818, X6CrNiSiNCe19-10).

Element Symbol Min % Max % Role in Alloy
Iron Fe Balance Base element
Chromium Cr 18.0 20.0 Oxidation resistance
Nickel Ni 9.0 11.0 Austenite stability
Silicon Si 1.2 2.0 Enhanced oxidation resistance
Nitrogen N 0.12 0.20 Creep / high-temperature strength
Cerium Ce 0.03 0.08 Oxide-scale adherence (rare earth)
Carbon C 0.04 0.08 Carbide strengthening
Manganese Mn 0.8 Deoxidiser
Phosphorus P 0.045 Residual impurity
Sulphur S 0.015 Residual impurity

Nominal: 19Cr-10Ni-Si-N-Ce heat-resistant steel. Silicon, nitrogen and cerium give improved oxidation resistance and creep strength over standard 1.4301-type grades, for service to ~1000 °C.

3. Mechanical Properties

Solution-annealed (+AT) condition, per EN 10088-2 for W.Nr. 1.4818.

Property Value Unit
Tensile strength (Rm) 600–800 MPa
0.2% proof strength (Rp0.2) ≥290 MPa
Elongation at fracture (A) ≥40 %
Brinell hardness ≤223 HB

Values per EN/DIN; confirm against the inspection certificate (EN 10204).

4. Oxidation and High-Temperature Resistance

Environment Performance Notes
Oxidation / scaling (dry air) Excellent To ~1000 °C (vs ~800 °C for 1.4301)
Oxide-scale stability Excellent Cerium + silicon
Sigma-phase resistance Good Cerium / nitrogen
High-temperature strength / creep Good Optimum ~600–950 °C
Cryogenic toughness Excellent Fully austenitic
Oxidizing sulphur-bearing gases Limited As noted by manufacturer
Embrittlement (600–900 °C, prolonged) Caution Possible on long exposure

5. Heat Treatment

An austenitic stainless steel; it cannot be hardened by heat treatment. Strength is increased only by cold work.

Solution Anneal approximately 1050–1150 °C, followed by rapid cooling (water quench or rapid air), to dissolve carbides and produce a uniform austenitic structure with optimum oxidation and creep behaviour.

Prolonged exposure in the ~600–900 °C range can lead to some embrittlement; ductility can be restored by re-solution-annealing followed by rapid cooling. The cerium and nitrogen additions help resist sigma-phase precipitation.

6. Weldability and Joining

Has good weldability and can be joined by submerged-arc, plasma-arc, flux-cored-arc, shielded-metal-arc, gas-tungsten-arc and gas-metal-arc processes. A matching or over-alloyed heat-resistant filler is used; preheating is not required.

Process Applicability Notes
GTAW / TIG · GMAW / MAG Good Matching/over-alloyed heat-resistant filler
SAW · PAW · FCAW · SMAW Good Heat-resistant consumable

No preheat required. Keep heat input controlled; solution anneal after welding where maximum high-temperature performance is required.

7. Machinability and Fabrication

Machining Guidelines

Parameter Recommendation
Machinability As for austenitic stainless; rigid tooling, positive feeds
Work hardening High; sharp tooling, avoid dwelling
Coolant Ample flood coolant

Forming Processes

Process Notes
Hot working ~1100–1150 °C; solution anneal after
Cold forming Readily formed; work-hardens
Solution anneal ~1050–1150 °C, rapid cool

8. Applications

Industry Typical Components Key Requirements
Heat treating / furnaces Furnace components, radiant tubes, muffles, fixtures Oxidation resistance to ~1000 °C
Automotive Exhaust and emission-control components Heat + oxidation resistance
Power / process Heat exchangers, recuperators High-temperature strength + creep
Conveyors / fixtures Heat-treatment baskets, conveyor parts Creep + thermal cycling
Cement / mineral High-temperature process equipment Oxidation + creep resistance
Cryogenic Low-temperature equipment Austenitic toughness

9. Available Product Forms and Standards

Product Form Standard Notes
Plate, sheet and strip EN 10095 / 10088-2 · W.Nr. 1.4818 X6CrNiSiNCe19-10
Bar, rod and semi-finished EN 10088-3 · W.Nr. 1.4818
Seamless / welded tube W.Nr. 1.4818
Composition / designation W.Nr. 1.4818 · X6CrNiSiNCe19-10 EN 10095

Heat-resistant Si-N-Ce austenitic stainless steel (19Cr-10Ni). W.Nr. 1.4818 (X6CrNiSiNCe19-10); EN 10095. (Variant of 1.4301 with increased Si, N and rare-earth metals.)

10. Comparison with Related Alloys (Werkstoff-Nummer System)

W.Nr. Nominal Max °C Best Used For
1.4818 19Cr-10Ni-Si-N-Ce ~1000 Heat-resistant 1.4301 upgrade (Si-N-Ce)
1.4948 18Cr-9Ni ~800 Standard heat-resistant austenitic
1.4835 21Cr-11Ni-Si-N-Ce ~1150 Higher-temp Si-N-Ce grade
1.4833 23Cr-13Ni ~1000 Higher-Cr/Ni heat-resistant
1.4845 25Cr-20Ni ~1050–1100 High-Cr/Ni heat-resistant


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